A: Invariably the reason for this defect is that there is an incompatibility between the two paints. Either the solvents being used in the new paint are incompatible with the old, or the resin of the new paint is sesitive to the overcoating time.
There are some resins which have critical overcoating time. For instance you can apply the new paint within two hours after the "old" one, AND you can apply it after six hours, but you cannot apply it between two and six hours. This is an incompatibility within the resin.
In your case it sounds as if you have incompatible solvents. It is likely that the solvents in the polyurethane are stronger ("hotter") than those in the vinyl acrylic.